Note
This website is presently under development. The primary website for MOPAC is still http://openmopac.net until the majority of its contents have been migrated here.
DENSITY
¶
At the end of a MOPAC job, when results are being printed, the density matrix is also printed. For RHF the normal density matrix is printed. For UHF the sum of the alpha and beta density matrices is printed.
If density is not requested, then the diagonal of the density matrix, i.e., the electron density on the atomic orbitals, will be printed.
Excited state density matrices¶
When an excited state is calculated using the MECI method (see
Multi-Electron Configuration Interaction method in
Theory) the corresponding density matrix is
constructed. Keywords that cause MECI to be used are
`C.I.=text
<ci=nm.html>`__, `OPEN
<open.html>`__,
`EXCITED
<excited.html>`__, and `MICROS
<micros.html>`__. When
DENSITY
is present, the excited state density matrix is printed.
The excited state used in constructing the density matrix is indicated
in the MECI output by a “+” sign next to the state number in the list of
state energies (state energies are printed when keyword
`MECI
<meci.html>`__ is present) For transition dipoles or
oscillator strength, also see the
polarization values in the MECI
output.